Here are three useful kit manufacturers that make relatively simple kits.
http://www.422modelmaking.co.uk.
http://www.smallbrookstudio.co.uk
http://www.peco-uk.com
My advice is to start by buying a budget little Hornby 0-4-0 trainset with a loco that has piston rods and pistons. The track can be used and the loco, and the wagon or 4 wheel coach chassis can be used (Mineral wagons and some others can be used as they are if one wants. Be aware that chassis can be cut in two to form sub chassis and filed to fit under coach or waggon kits so they can all come in useful. I have done this with a short wheelbase Hornby wagon chassis which is glued underneath one of my Smallbrook Studio 4 wheel coach kits as I did not have a suitable Dapol chassis which was recommended to be used at the time).
For beginners I recommend keeping to either the resin or pladtic kits. So for locos I would go for a Smallbrook kit, for coaches I would use any of the three manufacturers for coaches. Peco plastic coaches are pre coloured so no painting is required unless one want to paint them. For waggons I would go for Smallbrook or 422, though Peco vans are plastic so are suitable for beginners and I believe there larger mineral wagon is plastic too? (Check before buying). I am not saying one can't buy one of the whitemental kits. I am just saying that it is easier to start with plastic or resin.
My main recommendation in regards to loco kits is to make sure you have, or can get a suitable donor loco or chassis that can be used with the kit before you buy one just incase you may end up dissapointed. The little Hornby 0-4-0's are plentiful enough even if one has to use an older chassis that goes at 200mph! Haha. (Use the speed knob on the controller to slow it down. That's what its for!

Track. You can use standard 00 gauge or Peco 0-16.5 track or a mix (As long as it is code 100 to get the same rail height)). Your choice. 00 gauge sleepers can be hidden under ballast if required. You can't go wrong!
Well. What are you waiting for? Off you go and start building! Enjoy and good luck!